منابع مشابه
Hückel's Rule of Aromaticity Categorizes Aromatic closo Boron Hydride Clusters.
A direct connection is established between three-dimensional aromatic closo boron hydride clusters and planar aromatic [n]annulenes for medium and large boron clusters. In particular, the results prove the existence of a link between the two-dimensional Hückel rule, as followed by aromatic [n]annulenes, and Wade-Mingos' rule of three-dimensional aromaticity, as applied to the aromatic [Bn Hn ](...
متن کاملPhotoelectron spectroscopy of boron aluminum hydride cluster anions.
Boron aluminum hydride clusters are studied through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations. Boron aluminum hydride cluster anions, BxAlyHz(-), were generated in a pulsed arc cluster ionization source and identified by time-of-flight mass spectrometry. After mass selection, their photoelectron spectra were measured by a magne...
متن کاملBoron-induced hydrogen localization in the novel metal hydride LaNi(3)BH(x) (x = 2.5-3.0).
The crystal structure and hydrogenation properties of the intermetallic boride LaNi(3)B were investigated. The hydrogen-free compound has a novel structure with orthorhombic symmetry, space group Imma, a = 4.9698(8) A, b = 7.1337(8) A, c = 8.3001(9) A, and V = 294.26(7) A(3). Thermal gravimetrical analysis reveals a hydride phase that forms near ambient conditions within the compositional range...
متن کاملA comparison of boron hydride- and hydrocarbon-based thiol derivatives assembled on gold surfaces
The elements carbon and boron uniquely form extensive series of compounds with hydrogen; hydrocarbons and boron hydrides. In comparison to carbon, which forms various chainor ring-like structures, boron, an electron deficient element, forms quasi-aromatic clusters architecturally derivable from a twelve-vertex icosahedral unit. Herein, we focus on a comparison of hydrocarbon and boron hydride b...
متن کاملA di-substituted boron dication and its hydride-induced transformation to an NHC-stabilized borabenzene.
The intrinsic electron deficiency of borane derivatives stems from the presence of a low-lying empty p orbital on the boron atom. Methods to further increase the Lewis acidity of boranes include the incorporation of a boron atom into an anti-aromatic system and the introduction of electronwithdrawing groups, such as halogens, Lewis acidic elements, and cationic functionalities. Compared with th...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: J. Chem. Soc., Trans.
سال: 1881
ISSN: 0368-1645
DOI: 10.1039/ct8813900213